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催化劑(固體)與反應溶液處于不同相，反應在固-液相界面進行的氧化方法稱為多相催化臭氧氧化法。近年來，多相催化臭氧氧化技術已經成為去除水中高穩定性、難降解有機污染物的關鍵技術之一。利用固體催化劑協同臭氧氧化可以降低反應活化能或改變反應歷程，從而達到深度氧化、去除有機污染物的目的。<br /> <br /> 氧化還原反應的特征是在反應中有電子從一個物質(還原劑)轉移到另外一個物質上(氧化劑)3。任何化學物質的氧化還原特性都可以用標準氧化還原電位來確定。臭氧具有很高的標準氧化還原電位4，在所有的原子中僅比氟原子、氧原子、 *OH自由基低(如表2—1所示)，所以臭氧分子可以和大多數有機物發生氧化還原反應。這種反應能力在與某些無機物(如Fc2+或是I-1)的反應過程中也是非常重要的。但是，對于大多數的臭氧反應一般不發生直接的電子轉移．而是氧從臭氧分子轉移到其他物質。除了式(2—1)、式(2’2)的臭氧和過氧化氫離子或是臭氧與超氧離于自由基的反應以外，直接的電子轉移的反應是非常罕見的：<br /> <br /> <br /> 在大多數情況下，都是1個氧原子發生轉移，例如，臭氧與Fe2，的反應：<br /> <br /> <br /> 可以根據反應物的投加方式或是各相態之間的流動方式來定義反應器的類刑。根據反應物的投加方式，反應器分為：<br /> <br /> <br /> (1)非連續流或是間歇反應器<br /> <br /> (2)連續流反應器<br /> <br /> 根據流態的定義方式僅適用于連續流反應器類型，反應器可以分為理想反應器或是非理想反應器兩類。理想反應器又可分為兩種情況：<br /> <br /> (1)完全混合流反應器<br /> <br /> (2)推流反應器<br /> </div> <div class="prdkey"></div> <div class="pager"><div class="prevpage"><span>上一個：</span><a href="product_view_775_282.html">離子交換</a></div><div class="nextpage"><span>下一個：</span><a href="product_view_773_282.html">RO反滲透</a></div><div 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